Feb 25, 2015 · We demonstrate that linkers with distinct lengths and functionalities can be sequentially installed into PCN-700. Single-crystal to single-crystal transformation is realized so that the positions of the subsequently installed linkers are pinpointed via single-crystal X-ray diffraction analyses.

Jun 25, 2016 · Guided by the geometrical analysis, linkers with different lengths were installed into a parent PCN-700, giving rise to 11 new MOFs and each bearing up to three different functional groups in predefined positions.

May 16, 2024 · Luminescent thiazole-decorated metal−organic frameworks are versatile and multifunctional materials for diclofenac sodium detection and removal from wastewater.

Herein, we designed a flexible Zr-MOF system, namely PCN-700 series, for the realization of switchable catalysis in cycloaddition reactions of CO2 with epoxides. Their breathing behaviors were studied by successive single-crystal X-ray diffraction analyses.

PCN-700 matches up with four criteria for post-synthetic cluster metalation studies. (Fig- ure 1 c). Second, the reactive terminal -OH À /H 2 O ligands are directly exposed to the channels...

May 1, 2019 · The PCN-700 series represents a good example of Zr-bcu-MOFs [83], [118], [119]; Zhou et al. reported that the use of 2,2′-dimethylbiphenyl-4,4′-dicarboxylic acid (H 2 Me 2-BPDC), in combination with the in situ formation of Zr 6 clusters, led to the rational synthesis of a Zr-bcu-MOF, PCN-700-Me 2 [83].

Sep 15, 2023 · The linker installation enabled controllable adjustment of the pore volume and pore environment of the PCN-700 by tuning the properties of the installed linkers. The resulting daughter MOFs exhibited improved H 2 adsorption performance.

Jun 27, 2016 · Herein, we designed a flexible Zr-MOF system, namely PCN-700 series, for the realization of switchable catalysis in cycloaddition reactions of CO 2 with epoxides. Their breathing behaviors were studied by successive single-crystal X-ray diffraction analyses.

Aug 26, 2016 · Herein, we designed a flexible Zr-MOF system, namely PCN-700 series, for the realization of switchable catalysis in cycloaddition reactions of CO2 with epoxides. Their breathing behaviors were studied by successive single-crystal X-ray diffraction analyses.

Mar 11, 2015 · PCN-700, a Zr-MOF with eight-connected Zr6O4(OH)8(H2O)4 clusters, has been judiciously designed; the Zr6 clusters in this MOF are arranged in such a fashion that, by replacement of terminal OH(-)/H2O ligands, subsequent insertion of …