2019年12月11日 · UiO-66 is an archetypal metal–organic framework (MOF) with a very high surface area as well as high thermal stability. It is found that the stability can be attributed to the metal oxide node being cuboctahedral allowing for 12 extension points for 1,4-benzenedicarboxylic acid (BDC) coordination.

2023年6月15日 · Zirconium-based metal-organic framework (UiO-66) was successfully prepared by the solvothermal method using DMF as an organic linker at 120°C and characterized by FTIR, PXRD and TGA for functional groups, phase identification and thermal stability, respectively.

2022年4月1日 · Metal-organic frameworks (MOFs) have recently achieved much attention to eliminating toxic pollutants because of their attractive attributes, includin…

2011年3月4日 · UiO-66 (Zr-BDC) is one of the most promising MOFs for catalysis and photocatalysis because of its high stability, even in NaOH and HCl solutions. Solvent removal implies a distortion of the Zr6 ino...

2017年1月6日 · UiO-66 is an archetypal zirconium-based metal–organic framework (MOF) that is constructed from hexanuclear zirconium oxide clusters as secondary building units (SBUs) and 1,4-benzenedicarboxylate (bdc) linkers.

2025年1月3日 · Here, a novel high-entropy, defect-rich and small-sized (32 nm) UiO-66 (ZrHfCeSnTi HE-UiO-66) has been synthesized for the first time, leveraging increased configurational entropy to achieve...

2013年9月6日 · A scalable, reproducible method of synthesizing UiO-66- and UiO-67-type MOFs, entailing the addition of HCl to the reaction mixture, has been investigated. The new protocol requires a fraction of the time of previously reported procedures, yields exceptional porosities, and works with a range of linkers.

Zirconium 1,4-dicarboxybenzene MOF (UiO-66) | C48H28O30Zr6+4 | CID 162533375 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more.

2019年11月16日 · In this article, we review five approaches for fabricating UiO-66 polycrystalline membranes including in situ synthesis, secondary synthesis, biphase synthesis, gas-phase deposition and electrochemical deposition, as well as their applications in gas separation, pervaporation, nanofiltration and ion separation.

2024年2月26日 · UiO-66 ([Zr 6 O 4 (OH) 4 (bdc) 12]) is a popular UiO series MOF material that has been widely studied due to its high specific surface area, excellent structural stability, connected three-dimensional (3D) structure, and photo-responsiveness .