常用在顺式-双 (链烯基)环氧乙烷上引入大位阻的叔丁基二甲基硅基，促进室温 Cope 重排反应生成 2-CF3-4,5-二氢噁庚英；还可与与硫代坊共同用于促进快速高效的硫族化物-Morita-Baylis-Hillman 反应。 TOKYO CHEMICAL INDUSTRY CO., LTD.

This reagent was used to introduce a bulky tert -butyl dimethylsilyl group onto a cis -bis (alkenyl)oxirane facilitating a room temperature Cope rearrangement to a 2-CF 3 -4,5-dihydrooxepin. [1] Together with a thiolane promotes a rapid and efficient chalcogenide-Morita-Baylis-Hillman reaction. [2] Choose from one of the most recent versions:

tert-Butyldimethylsilyl Triflate (=TBSOTf) [T1525] 2,6-Lutidine [L0067] α,α-Diphenyl-D-prolinol [D2365] Dichloromethane; Procedure. TBSOTf (1.36 mL, 5.92 mmol, 3.0 eq.) was added to a solution of α,α-diphenyl-D-prolinol (500 mg, 1.97 mmol) and 2,6-lutidine (1.4 mL, 11.8 mmol, 6.0 eq.) in dichloromethane (10 mL) at 0 °C. The mixture was ...

2023年4月4日 · 叔丁基二甲硅基三氟甲磺酸酯是高活性硅化剂和Lewis酸，能够将伯、仲、叔醇转化为相应的TBDMS醚，并将酮和内酯转化为相应的烯醇硅基醚；促进烷基锌化合物和三苯基膦与α、β-烯酮的共轭加成； [4 +2]环加成反应中染色质的活化吡啶环向格氏试剂的活化和叔胺N-氧化物的反式烷基化N-叔丁氧基羰基转变为N-烷氧基。 伯醇、仲醇和叔醇通过与叔丁基二甲硅基三氟甲磺酸酯反应进行硅烷化，收率极佳。 通过用1-2当量的TBDMS三氟甲磺酸酯和1.5当量的三乙胺 …

叔丁基二甲硅基三氟甲磺酸酯（TBS triflate）是一种有机化合物。 以下是关于TBS triflate的性质、用途、制法和安全信息的介绍： - 外观：TBS triflate为无色至浅黄色液体。 - 溶解性：可溶于多数有机溶剂，如乙醚、二氯甲烷和苯等。 - 稳定性：在常温下相对稳定。 - TBS triflate在有机合成中被广泛应用作为一种有效的保护基。 它可用于保护醇、醚和胺等化合物，以防止其在反应中发生意外改变。 - 它也可以作为氟化试剂，在一些特定化学反应中起催化剂或活化剂的作用。 - TBS …

Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice. * To send your quote request for bulk quantities, please click on the "Request Quote" button. Please note that we cannot offer bulk quantities for some products.

2024年1月2日 · 催化chalcogenide-Morita-Baylis-Hillman 反应。 反应中引入叔丁基二甲基硅烷基基团。 存放在密封容器内，并放在阴凉，干燥处。 储存的地方必须远离水源，远离碱存放，切 …

Use this link for bookmarking this species for future reference. The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected …

这种试剂用于在顺式-双 (链烯基)环氧乙烷上引入大位阻的叔丁基二甲基硅基，促进室温 Cope 重排反应生成 2-CF 3 -4,5-二氢噁庚英。 没有发现合适的版本？ 已有该产品？ 在文件库中查找您最近购买产品的文档。

tert-Butyldimethylsilyl trifluoromethanesulfonate is involved in the introduction of a bulky tert-butyl dimethylsilyl group onto a cis-bis (alkenyl)oxirane used in Cope rearrangement. It is associated with a thiolane and promotes the chalcogenide-Morita-Baylis-Hillman reaction. Further, it is used as a highly reactive silylating agent.