The MIL-53 structure consists of inorganic [M-OH] chains, which are connected to four neighboring inorganic chains by therephthalate-based linker molecules. Each metal center is octahedrally coordinated by six oxygen atoms.

MIL-53是一种金属有机框架材料，名称中字母缩写MIL为Matériaux de l′Institut Lavoisier，它由圣康丁昂伊夫利纳-凡尔赛大学拉瓦锡研究所的Gérard Férey组所合成。

2021年1月1日 · MIL-53 is a metal organic framework (MOF) belonging to the MIL (Material Institute Lavoisier) group. It is a 3-D framework, built up by the combination of metal salt (Al, Fe, Cr) and linker (terephthalic acid). It is well known for its …

2021年1月27日 · 在数百种不同MOF中，对苯二甲酸铝，即大家熟知的MIL-53(Al) MOF（13-3050），是常研究的有机-无机杂化材料之一。这种材料由来自Lavoisier Institute of Versailles University（法国）的Gérard Férey教授合成。

2022年6月29日 · The present work introduces a detailed molecular-level mechanism of the formation of MIL-53(Al), unraveled by combining in situ time-resolved high-resolution mass-spectrometry, magic angle ...

实验结果表明，有机金属骨架MIL－53系列独特的骨架呼吸特性使其具有良好的储氢. 性能，且具有较高比表面积、孔容及孔径的MIL－53（Al）在储氢性能方面具有更好的表现。 关键词： MIL－53； 合成； 表征； 呼吸特性； 储氢性能

2025年3月7日 · Q-MIL-53(Fe), MIL-53(Fe)-400, and MIL-53(Fe)-500 were prepared in traditional pyrolysis in a tube furnace under N 2 atmosphere at 350, 400, or 500 °C for 1 h with a ramp rate of 3 °C min −1 ...

本发明采用的金属有机骨架材料mil-53(al)的合成方法，以水不溶性氢氧化铝为铝源，合成过程中加入一定比例的酸助剂，在降低反应温度的情况下保持较高的产率，水热条件下，酸助剂与氢氧化铝作用，提高了氢氧化铝在反应体系中的溶解性，提高了铝源的反应 ...

MIL-53(Fe) (MIL: Materials of Institute Lavoisier), a class of MOFs generated by a combination between iron(III) cations and 1,4-dicarboxylic acid, consists of three-dimensional networks or secondary building units which contain FeO 6 hexagonal chains and dicarboxylate anions .

2018年9月3日 · We present a review of the structural chemistry of metal-organic framework materials with the MIL-53 type structure. This family of materials is well-known for its structural flexibility, and also the wide variety of metal cations and functional ligands that can be included.