2022年8月22日 · In this Review we survey the molecular sieving behaviour of metal–organic framework (MOF) and covalent organic framework (COF) membranes, which is different from that of classical zeolite...

2021年3月4日 · What is the difference between a MOF and a COF? A metal organic framework can be pictured as a combination of metal atoms (or clusters) as nodes, with organic linkers. In a COF (or Covalent Organic Framework) these metal ‘nodes’ are instead replaced by a non-metal such as boron or nitrogen.

2021年7月7日 · In this review, we provide an overview of significant progress in the design and synthesis of MOF/COF hybrids, including MOF@COF, COF@MOF, MOF + COF, C-MOF, and COF-in-MOF, and their various applications in catalysis, gas adsorption, sensing, energy storage, and photodynamic therapy.

2021年12月3日 · On the basis of our group’s research, this paper provides a detailed discussion of the design, synthesis, and mechanistic analysis of MOF-COF photocatalysts. First, we discuss MOF-COF heterojunction structures that can improve the photocatalytic properties of …

2021年5月14日 · Leveraging the unique properties of reticular materials has resulted in significant advances from both a fundamental and an applied perspective. This Review reports on the milestones in MOF and COF research and gives a critical view on …

2022年12月1日 · With the development of synthesis techniques between MOFs and COFs over the past several years, MOF/COF composites prepared by combining MOFs and COFs have become an emerging class of porous hybrid materials. Herein, we first comprehensive summarize advanced strategies for synthesizing MOF/COF composites.

New MOF/COF hybrids combine the outstanding features of MOF and COF structures, such as high crystallinities, large surface areas, high porosities, the ability to decorate the structures with functional groups, and improved chemical and mechanical stabilities.

2021年1月4日 · Covalent organic frameworks (COFs) are promising materials for advanced molecular-separation membranes, but their wide nanometer-sized pores prevent selective gas separation through molecular...

2022年9月29日 · In this work, we prepared various MOF@COF composites with different COF layer thicknesses, in which stable UiO-66-NH 2 served as the inner substrate and 1,3,5-benzenetricarboxaldehyde (BT), and 3,3′-dihydroxybenzidine (DH) were used to …

2025年2月20日 · A new type of covalently connected MOF/COF photocatalytic system based on NH2-MIL-125(Ti) and TpBpy-COF was synthesized. As confirmed, the exposed crystal facet of MOFs greatly affected the resultant activity of MOF/COF system. The combination of decahedron NH2-MIL-125(Ti) and TpBpy-COF shows an optimal OWS activity with the H2 and O2 evolution ...