The benzaldehyde oxidation paradox explained by the ... - Nature
2014年2月25日 · Benzaldehyde readily undergoes autoxidation to form benzoic acid on exposure to air at room temperature. Yet it can be formed in high yield from, for example, benzyl alcohol …
MIL-101 as Reusable Solid Catalyst for Autoxidation of Benzylic ...
Product distribution and quenching experiments with 2,2,6,6-tetramethyl-1-piperidinyloxy, benzoic acid, and dimethylformamide show that the reaction mechanism is a radical chain autoxidation …
Benzaldehyde readily undergoes autoxidation to form benzoic acid on exposure to air at room temperature. Yet it can be formed in high yield from, for example, benzyl alcohol by oxidation …
An efficient and practical aerobic oxidation of benzylic …
An efficient and practical benzylic aerobic oxidation catalyzed by cheap and simple N-hydroxyimide organocatalyst has been achieved with high yields and broad substrate scope. …
Efficient and selective oxidation of tertiary benzylic CH bonds …
2020年6月5日 · To achieve the selective oxidation of tertiary benzylic C H bonds to alcohols under mild conditions, suitable reaction temperature is a key point needed to be considered, …
The benzaldehyde oxidation paradox explained by the …
2014年2月25日 · Benzaldehyde readily undergoes autoxidation to form benzoic acid on exposure to air at room temperature. Yet it can be formed in high yield from, for example, benzyl alcohol …
The benzaldehyde oxidation paradox explained by the …
2014年2月25日 · Benzaldehyde readily undergoes autoxidation to form benzoic acid on exposure to air at room temperature. Yet it can be formed in high yield from, for example, benzyl alcohol …
Selective benzylic C–H monooxygenation mediated by iodine oxides
The installation of oxygen functionality at benzylic C–H bonds allows for the production of benzylic alcohols, aryl ketones, and aryl carboxylic acids, which are useful chemical building blocks. …
Co/NHPI-mediated aerobic oxygenation of benzylic C–H bonds in ...
2017年2月1日 · Here, we explore Co/NHPI-catalyzed benzylic 12 oxygenation reactions of substrates bearing common heterocycles, such as pyridines, benzimidazoles and thiophenes, …
Here, we explore Co/NHPI-catalyzed benzylic 12 oxygenation reactions of substrates bearing common heterocycles, such as pyridines, benzimidazoles and thiophenes, and benzylic …