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Ionic fragmentation of a natural product, limonene (C10H16), …
2007年3月1日 · In the present paper we investigate the fragmentation of the limonene molecule at high photon energy and following core [C 1s] ionization. A He(I) time-of-flight mass spectrum is also presented, as a reference towards the analysis of the photon induced fragmentation of the limonene molecule.
Ionic fragmentation of a natural product, limonene (C 10H 16 ...
2007年3月1日 · We have shown, for instance, that the degree of ionic fragmentation of monoterpenes such as carvone, C 10 H 14 O [4], limonene, C 10 H 16 [5] and camphor, C 10 H 16 O [6], increases strongly...
Fragmentation pathway of limonene obtained by a MS n PTR-LIT …
We performed MS/MS investigations of biogenic volatile organic compounds (BVOC) using a triple quadrupole tandem mass spectrometer (QqQ-MS) equipped with a Townsend Discharge ion source and a...
(PDF) Ionic fragmentation of a natural product, limonene …
In the present paper we investigate the fragmentation of the limonene molecule at high photon energy and following core [C 1s] ionization. A He(I) time-of-flight mass spectrum is also presented, as a reference towards the analysis of the photon induced fragmentation of the limonene molecule.
Time-of-flight mass spectra of the limonene molecule obtained …
In the present paper we investigate the fragmentation of the limonene molecule at high photon energy and following core [C 1s] ionization. A He (I) time-of-flight mass spectrum is also...
Photoelectron Circular Dichroism in the Photodetachment of …
3 天之前 · As proof of concept, vapors contg. ∼1% of two chiral monoterpene mols., limonene and camphor, are irradiated by a circularly polarized femtosecond laser, resulting in multiphoton near-threshold ionization with little mol. fragmentation. Large chiral asymmetries (2-4%) are obsd. in the mass-tagged photoelectron angular distributions.
Ionic fragmentation of a natural product, limonene (C10H16), …
2007年3月1日 · The origins and nature of the [C5H8]+⋅ ions which form the base peak in the electron impact spectrum of limonene, at nominal electron energies greater than 11 eV, have been investigated. Linked scan …
Exploring the unimolecular chemistry of protonated limonene and …
2024年4月1日 · Protonated limonene undergoes two minor dissociation pathways that eliminate propane and ethene. Unlike prenol, protonation on the hydroxy group of terpineol forms a stable ion. Water loss from terpineol reforms protonated limonene.
Energetics of retro‐Diels–Alder fragmentation in limonene as ...
Isomerization, occurring through 1,3-hydrogen migrations of the molecular ions of limonene, isolimonene, terpinolene and α-terpinene, was investigated and long-lived molecular ions of the first three compounds were found to maintain distinct structures.
Ionic fragmentation of a natural product, limonene (C10H16), …
2007年3月1日 · In the present paper we investigate the fragmentation of the limonene molecule at high photon energy and following core [C 1s] ionization. A He(I) time-of-flight mass spectrum is also presented, as a reference towards the analysis of the photon induced fragmentation of the limonene molecule.