The first noncentrosymmetric (NCS) rare earth fluoroiodate, CaCe(IO3)3(IO3F)F, has been hydrothermally synthesized through rational chemical substitution. Substituting one IO3− group with one IO3F2− unit and two Li+ cations with a Ca2+ cation in Li2Ce(IO3)4F2 transforms the symmetry from centrosymmetric (CS)

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2023年10月17日 · An optically anisotropic alkali-earth-metal gallium fluoroiodate, Ba2[GaF5(IO3F)] (1), was ingeniously obtained by integrating fluoride and fluoroiodate functional units under moderate hydrothermal...

2021年6月9日 · A novel salt-inclusion fluoroiodate [GaF(H2O)][IO3F] derived from CsIO2F2 was ingeniously obtained through anisotropic polycation substitution. Because the catenulate [GaF(H2O)]2+ framework serves as a template for the favorable assembly of the polar [IO3F]2− groups and contributes to the nonlinear coefficie 2021 Chemical Science HOT Article ...

通过各向异性聚阳离子取代，巧妙地获得了一种衍生自CsIO 2 F 2的新型含盐氟碘酸盐 [GaF (H 2 O)] [IO 3 F] 。 因为链状 [GaF (H 2 O)] 2+框架作为有利组装极性 [IO 3 F] 2−基团的模板，并有助于非线性系数， [GaF (H 2 O)] [IO 3 F]与母体化合物 CsIO 2 F相比，其二次谐波产生 (SHG) 效应显着提高，是 KH 2 PO 4 (KDP)的 10 倍，带隙为 4.34 eV2（3 × KDP，4.5 eV）。 特别是，据我们所知， [GaF (H 2 O)] [IO 3 F] 具有最大的激光诱导损伤阈值 (LDT)，为 140 × AgGgS 2报告 …

A novel salt-inclusion fluoroiodate [GaF(H 2 O)][IO 3 F] derived from CsIO 2 F 2 was ingeniously obtained through anisotropic polycation substitution. Because the catenulate [GaF(H 2 O)] 2+ framework serves as a template for the favorable assembly of the polar [IO 3 F] 2− groups and contributes to the nonlinear coefficient, [GaF(H 2 O)][IO 3 F] …

第一个非中心对称（NCS）稀土氟碘酸盐CaCe (IO 3 ) 3 (IO 3 F)F已通过合理的化学取代水热合成。 在Li 2 Ce (IO 3 ) 4 F 2中用一个IO 3 F 2-单元和两个Li +阳离子用一个Ca 2+阳离子取代一个IO 3 -基团，将对称性从中心对称 (CS) 转变为NCS。 CaCe (IO 3 ) 3 (IO 3 F)F在极空间群Pna 2 1中结晶并具有由 IO 3 F 2-单元桥接的 Ce 4+阳离子组成的新型二维 [Ce (IO 3 F)] 2+层。

A novel salt-inclusion fluoroiodate [GaF (H2O)] [IO3F] derived from CsIO2F2 was ingeniously obtained through anisotropic polycation substitution.

最近，一篇题为“Optically Anisotropic Mixed-Metal Fluoroiodate Ba2[GaF5(IO3F)] with a Wide Optical Transparent Window and a Moderate Birefringence”的论文在《无机化学》杂志上发表。该论文介绍了一种新型的光学异性碱土金属镓氟碘酸盐，命名为Ba2[GaF5(IO3F)]（1）。

2023年10月30日 · An optically anisotropic alkali-earth-metal gallium fluoroiodate, Ba 2 [GaF 5 (IO 3 F)] ( 1 ), was ingeniously obtained by integrating fluoride and fluoroiodate functional units under moderate hydrothermal conditions.