2024年5月28日 · HIO4 (periodic acid) is commonly used in organic synthesis to cleave vicinal diols to aldehydes and ketones, a process known as periodate cleavage. This reaction is useful for structural ...

2024年5月22日 · HIO4 is an iodine oxoacid widely referred to as periodic acid (in Dutch: Periodsaeure, and Ueberiodsaeure) and hyperiodic acid (as HIO4). It is also referred to as tetraoxoiodic acid, and by the ...

2024年6月1日 · HIO4(aq) stands for periodic acid, which is a strong oxidizing agent commonly used in organic chemistry for oxidation reactions. It is a colorless, crystalline solid when in pure form and is ...

2019年12月20日 · $\ce{HIO4_{(aq)}}$ requires the vicinal diols to have syn configuration, as it forms a cyclic periodate ester. But glucose does not have syn configuration at C3 , and if you consider cyclic forms of glucose it shouldn't oxidise fully at all because alternate hydroxy groups with anti configuration will be unreactive.

2016年8月14日 · $\ce{HBrO4}$ and $\ce{HIO4}$ both have the acidic proton bound to oxygen: The H-O bond is approximately of equal strength in both acids and therefore you turn to electronegativity arguments.

2015年4月30日 · Carbohydrate like glucose undergoes periodic cleavage by $\ce{HIO4}$ and forms respective products are five moles of formic acid and one mole of formaldehyde. Here is my question , what is mechanism and what are the products by fructose with the same?

2024年6月1日 · HIO4 (periodic acid) is commonly used in organic synthesis to cleave vicinal diols to aldehydes and ketones, a process known as periodate cleavage. This reaction is useful for structural ...

2020年8月21日 · The presence of several pairs of vicinal diols such as those in glucose during oxidation with $\ce{HIO4}$ can lead to the formation of complex product mixtures: Accordingly, the oxidation reaction of D-glucose with 5 equivalents of $\ce{HIO4}$ gives five equivalents of formic acid and one equivalent of formaldehyde (Figure A).

I'm looking for standard half-cell reduction potential $\ce{IO4-}$/$\ce{I2}$ in acid medium. Unfortunately I was unable to find the value in all comprehensible reference books.

Periodic acid (per-iodic acid, $\ce{HIO4}$ ) cleaves vicinal diols(to carbonyls) via a cyclic intermediate. Due to the cyclic intermediate, it needs a syn configuration for the $\ce{-OH}$ groups for the reaction. Exactly which configurations are allowed on cyclohexane derivatives? Let's take 1,2-dihydroxycyclohexane(boat conformer).