2025年3月1日 · UiO-67 species, a prominent class of metal-organic frameworks (MOFs) within the UiO (University of Oslo) subgroup, possess unique features.

2021年10月15日 · UiO-67 material doped by Pd(II) catalyses the reaction of aryl chlorides with olefins gave high yield through Heck and Suzuki–Miyaura coupling reactions.

2016年2月19日 · The structure and properties of two new UiO-67-type metal–organic frameworks, along with their linker synthesis and powder and single crystal synthesis, are presented.

2013年9月6日 · A scalable, reproducible method of synthesizing UiO-66- and UiO-67-type MOFs, entailing the addition of HCl to the reaction mixture, has been investigated. The new protocol requires a fraction of the time of previously reported procedures, yields exceptional porosities, and works with a range of linkers.

We report a hafnium-containing MOF, hcp UiO-67 (Hf), which is a ligand-deficient layered analogue of the face-centered cubic fcu UiO-67 (Hf). hcp UiO-67 accommodates its lower ligand:metal ratio compared to fcu UiO-67 through a new structural mechanism: the formation of a condensed “double cluster” (Hf 12 O 8 (OH) 14), analogous to the condensat...

2018年12月28日 · The thiol-equipped UiO-67 scaffold shows substantial stability toward oxidation, e.g., it can be treated with 30% H 2 O 2 to afford oxidation of the thiol to the strongly acidic sulfonic function while maintaining the ordered porous MOF structure.

2017年6月15日 · We present here for the first time the synthesis of UiO-67 and an iso-structural UiO-67-bpy by mechanochemistry. The materials were obtained in short reaction time, with a high purity confirmed by TGA analysis. The porosity of the materials was confirmed by …

2021年11月19日 · A well intergrown UiO-67 membrane with preferential growth along the [022] direction, results in more interconnected trans-membrane channels for ion transport, shows ultrahigh Li + ion permeability and excellent Li + /Mg 2+ selectivity.

2021年11月1日 · TP-IR studies revealed that under cryogenic UHV conditions, UiO-67-X MOFs are stable towards ammonia sorption. Interestingly, an increase in the intensity of the C−H stretching mode of the MOF linkers was detected upon ammonia exposure, attributed to NH−π interactions with linkers.

2024年6月28日 · Compared with the catalysts of Pd/UiO-66 and Pd/ZrO 2, Pd/UiO-67 catalyst boosted an excellence catalytic performance for toluene degradation, giving the lowest T 90% value of 235 °C with long-term stability.