C&EN23 天
Overcoming the Limited Reactivity of 1-Naphthaldimine in C–H Alkylation with Alkyl ...
Jiangsu Key Laboratory for Functional Substances of Chinese Medicine, School of Pharmacy, Nanjing University of Chinese Medicine, Nanjing, Jiangsu 210023, China ...
C&EN28 天
Room-Temperature Rh(I)-Catalyzed P(III)-Directed C–H Bond Alkylation: Enhanced Reactivity ...
In this study, we introduce a ligand-accelerated catalysis approach that enables room-temperature C–H bond alkylation of biarylphosphines using a Rh(I) catalyst. Through kinetic investigation, we ...